Product ID:7132 BLACK, 8047811
MSDS Date:04/27/1999
FSC:7510
NIIN:01-152-8728
Status Code:A
MSDS Number: CJTVV

MARKEM CORPORATION

150 CONGRESS STREET
KEENE, NH 03431
US

Emergency Phone: 703-527-3887 (COLLECT)

Info Phone: 603-352-1130

Preparer: THOMAS J. LEWIS

Cage: 38360

MARKEM CORPORATION

KEENE, NH 03431 US

Telephone: 603-352-1130

Cage: 38360

0%.

CAS: 61789-51-3

RTECS: QK8925000

ACGIH TLV: 0.1 MG/M3

1 G/ML.

CAS: 27253-31-2

<0.01 MMHG.

CAS: 124-17-4

RTECS: KJ9275000

STODDARD SOLVENT; (ODORLESS MINERAL SPIRITS).

CAS: 8052-41-3

RTECS: WJ8925000

OSHA PEL 2900 MG/M3;500 PPM

ACGIH TLV: 525 MG/M3;100 PPM

BIS(TRIBUTYLTIN) OXIDE

CAS: 56-35-9

RTECS: JN8750000

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

DIETHYLENE GLYCOL MONOMETHYL ETHER

CAS: 111-77-3

RTECS: KL6125000

METHYL ETHYL KETOXIME

CAS: 96-29-7

RTECS: FL9275000

LD50 LC50 Mixture:SEE INGREDIENTS & TOX INFO.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE CONTACT: CAN CAUSE MINOR
IRRITATION, TEARING AND REDDENING. SKIN CONTACT: CAN CAUSE MINOR
IRRITATION, DEFATTING AND DERMATITIS. SKIN ABSORBTION: MINIMAL
HAZARD IN NORMAL INDUSTRIAL USE. INH ALATION: CAN CAUSE RESPIRATORY
IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE AND
POSSIBLE UNCONSCOIUSNESS. INGESTION: IRRITATING TO MOUTH, THROAT
AND STOMACH. CAN CAUSE ABDOMINAL DISCOMFO RT, NAUSEA, VOMITING AND
DIARRHEA. CHRONIC: TARGET ORGANS: KIDNEYS; EYES; SKIN;RESPIRATORY
TRACT; NERVOUS SYSTEM; HEART; BLOOD; PANCREAS.
Explanation of Carcinogenicity:COBALT NAPHTHENATE: IARC MONOGRAPHS, VOL
52, PG 363, 1991: GROUP 2B.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NO DATA FOUND.

First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 20 MINS
RETRACTING LIDS OFTEN. GET IMMED MED ATTN. SKIN:WASH W/SOAP &
WATER. REMOVE CONTAM CLTHG & LAUNDER GET MED ATTN IF IRRIT
DEVELS/PERSISTS. INHAL:RE MOVE TO FRESH AIR. IF NOT BRTHG,
PERFORMRESCUE BRTHG &, IF AVAIL, HAVE TRAINED PERS ADMIN OXYG. GET
MED ATTN IMMED. INGEST:EMER PERS SHOULD BE CONTACTED IMMED & BE
PROVIDED W/THIS MSDS. FOR INGEST OF SM QTYS OF CHEMS, RISK ASSOC
W/INDUCING VOMIT USUALLY EXCEEDS POIS RISK. GET MED ATTN IMMED.
DRINK 2 GLASSES OF WATER. CONT POIS INFO SERVICES. STOM EVACUATION
MAY BE APPROP, AS REC BY MED PROFESSIONA LS, ONLY IF SIGNIFICANT
QTY OF (SUPDAT)

Flash Point:=113.9C, 237.F
Autoignition Temp:=232.2C, 450.F
Lower Limits:0.7%
Upper Limits:5.0%
Extinguishing Media:USE ALCOHOL FOAM, CARBON DIOXIDE (CO*2) OR DRY
CHEMICAL. WATER MAY NOT BE EFFECTIVE TO EXTINGUISH FIRE. USE WATER
SPRAY TO COOL FIRE-EXPOSED CONTAINERS AND TO PROTECT PERSONNEL.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
FIGHT FIRE FROM SAFE DIST & PROTECTED LOCATION. HEAT MAY BUILD
PRESS & RUPTURE CLSD CNTNRS, SPREADING FIRE & INCR RISK OF
BURN/INJURIES. WATER MAY BE IN EFT IN FIREFIGHTING DUE TO LOW FLASH
POINT & LTD MISCIBILITY W/WATER. FLAMM/COMBUST COMPONENTS OF THIS
MATL (OTHER INFO)
Unusual Fire/Explosion Hazard:VAPS MAY BE IGNITED BY HEAT,
SPKS,FLAME/OTHER SOURCES OF IGNIT GIVING RISE TO CLASS B FIRE. VAPS
ARE HVR/AIR & MAY TRAVEL TO SOURCE OF IGNIT & FLASH BACK. CNTNR MAY
EXPLODE IN HEAT OF FIRE. EMPTY CNTN R MAY STILL CONTAIN RESIDUAL
MATL THAT CAN IGNITE &/OR RSLT IN EXPLO. DO NOT PRESSURIZE, CUT,
WELD, BRAZE, (SUPP DATA)

Spill Release Procedures:SHUT OFF IGNIT SOURCES; SMOKING, FLAMES/OTHER
SOURCES OF IGNIT MUST NOT BE PERMITTED IN AREA. SM SPILLS:TAKE UP
W/SAND OR OTHER NONCOMBUST ABSORB MATL & PUT INTO PROPERLY LABELED
CNTNRS FOR DISP. LG S PILLS:DIKE AHEAD OF LIQ SPILL AREA TO MIN
MIGRATION & VAP GENERATION. VENT AREA. GET PROFESSIONAL HELP FROM
OUTSIDE CONTRACTORS, FIRE DEPT/YOUR TRAINED SPILL BRIGADE. FOLLOW
GUIDELINES OF (OTHER INFO)

Handling and Storage Precautions:STORE IN A COOL, DRY VENTILATED
LOCATION, AWAY FROM SOURCES OF IGNITION OR OTHER INCOMPATIBLE
CONDITIONS. KEEP CONTAINER(S) CLOSED IF POSSIBLE.
Other Precautions:AVOID CONTACT WITH MATERIAL, AVOID BREATHING VAPORS,
USE ONLY IN A WELL VENTILATED AREA, USE BONDING AND GROUNDING WHEN
TRANSFERRING THIS MATERIAL.

Respiratory Protection:IF AIR MONITORING INDICATES AIRBORNE
CONCENTRATIONS AT OR ABOVE LIMITS, OR SYMPTOMS OF INHALATION
OVEREXPOSURE OCCUR, A NIOSH APPROVED RESPIRATORY PROTECTION PROGRAM
MAY BE REQUIRED. ENGINEERING CONTR OLS TO REDUCE THE EXPOSURE BELOW
ACCEPTABLE LIMITS ARE USUALLY PREFERABLE TO A RESPIRATOR PROGRAM.
Ventilation:LOC EXHST VENT/OTHER ENGINEERING CONTROLS ARE NORMALLY REQD
WHEN HNDLG/USING THIS PROD TO KEEP EXPOS TO AIRBORNE CONTAMS BELOW
TLV, PEL/OTHER (ECOLOGICAL INFO)
Protective Gloves:IMPERVIOUS GLOVES . INSPECT FOR CHEM BREAK-THRU &
REPLACE IF DETECTED.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . PREVENT SKIN CONTACT BY WEARING OTHER PROTECTIVE
EQUIPMENT. CLEAN EQUIPMENT THOROUGHLY AFTER EACH. DO NOT REMOVE
FROM WORKPLACE.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN.
Supplemental Safety and Health
FIRST AID PROC:MATLS HAS BEEN INGESTED. STOM EVACUATION SHOULD ONLY BE
CARRIED OUT BY TRAINED & PROPERLY EQUIPPED MED PERS. -- EXPLO
HAZ:SOLDER, DRILL, GRIND/EXPOSE EMPTY CNTNR TO HEAT, FLAME, SPKS,
STATIC ELEC/OTHER SOURCES OF IGNIT. HMIS/NFPA RATINGS:HLTH-2;
FLAMM-1; REACT-1, PROTECTION(HMIS):B.

Boiling Pt:>157.2C, 315.F
B.P. Text:315-455F
Melt/Freeze Pt:M.P/F.P Text:NOT DETERMINED
Vapor Pres:<0.01 MMHG & SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.2 G/ML & SEE INGS
pH:NOT DETERMINED
Viscosity:NOT DETERMINED
Evaporation Rate & Reference:0.01-0.1(N-BUAC=1) & INGS
Solubility in Water:SEE INGREDIENTS
Appearance and Odor:BLACK LIQUID.
Percent Volatiles by Volume:13

Stability Indicator/Materials to Avoid:YES
ACIDS; CAUSTICS (BASES); STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS. AVOID
HEAT, SPARKS, OPEN FLAME, OTHER IGNITION SOURCES, OXIDIZING
CONDITIONS AND ELEVATED TEMPERATURES.
Hazardous Decomposition Products:HAZARDOUS DECOMPOSITION/COMBUSTION
PRODUCTS: CARBON DIOXIDE; CARBON MONOXIDE.

Waste Disposal Methods:POTENTIAL EPA WASTE CODE(S): NOT DETERMINED.
DISPOSE OF BY INCINERATION OR WASTE WATER TREATMENT FOLLOWING
FEDERAL, STATE, LOCAL OR PROVINCIAL REGULATIONS. RCRA: NO
COMPONENTS (SUBSTANCES) ARE SUBJECT TO RCRA LAND DISPOSAL
RESTRICTIONS.

Toxicological Information:ODORLESS MINERAL SPIRITS: LC50:(RAT) >5500
MG/KG (880 PPM) (WHOLE BODY EXPOSURE FOR 4 HOURS). LC50:(RAT) >8200
MG/M3 (1300 PPM). LD50:(DERMAL,RABBIT) >3 G/IKG. CANCER
INFORMATION: CONTAINS A SUBSTANCE THAT CAN CAUSE CANCER IN
LABORATORY ANIMALS AT HIGH ORAL DOSES. REPRODUCTIVE SYSTEM
INFORMATION: NONE OF THE SUBSTANCES HAVE BEEN SHOWN TO CAUSE
REPRODUCTIVE SYSTEM DISORDERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO INFORMATION AVAILABLE. -- OTHER INFO: CONSIDER THAT THE
EVAPORATION OF VOLATILE SOLVENTS CAN LEAD TO THE DISPLACEMENT OF
AIR CREATING AN ENVIRONMENT THAT CAN CAUSE ASPHYXIATION. -- VENT:
RECOMMENDE D EXPOSURE LIMIT AND/OR MAINTAIN OPERATOR COMFORT. THESE
CONTROLS SHOULD BE EXPLOSION-PROOF WHEN EXHAUSTING FLAMMABLE
VAPORS.

Transport Information:DOT & IATA: NOT RESTRICTED.

SARA Title III Information:CERCLA: THE FOLLOWING COMPONENTS HAVE CERCLA
REPORTABLE QUANTITIES (RQ'S): NO CERCLA RQ CHEMICALS. SARA TITLE
III: THE FOLLOWING COMPONENTS ARE LISTED UNDER SECTION 313: NO SARA
313 CHEMICALS.
Federal Regulatory Information:IF THE TOTAL PERCENTAGE IS <100, THE
BALANCE OF THIS PROD IS NOT CONSIDERED TO BE HAZ AS DEFINED IN OSHA
HAZ COMMUNICATION STD (29 CFR 1910.1200). WHMIS: FOLLOWING
COMPONENTS ARE WHMIS WORKPLACE HAZ M ATLS: BIS(TRIBUTYLTIN) OXIDE -
CAS # 56-35-9 - <1%; CARBON BLACK - CAS # 1333-86-4 - <0.1%;
DIETHYLENE GLYCOL MONOMETHYL ETHER - CAS # 111-77-3 - <1%; STODDARD
SOLVENT - CAS # 8052-41-3 - 1-5%. TSCA: ALL CHEMS IN THIS PROD ARE
ON USEPA TSCA 8(B) INVENTORY. TSCA: FOLLOWING COMPONENTS ARE
SUBJECT TO T SCA 12(B) REGS: 2,(2-BUTOXYETHOXY)ETHYL ACETATE - CAS
# 124-17-4 - 5-10%; METHYL ETHYL KETOXIME - CAS # 96-29-7.